Experimental adsorption parameters of boron isotopes on clay minerals

Cite as:

Ring, Simon J.; Henehan, Michael J.; Blukis, Roberts; von Blanckenburg, Friedhelm (2024): Experimental adsorption parameters of boron isotopes on clay minerals. GFZ Data Services. https://doi.org/10.5880/GFZ.3.3.2024.003

Status

I N R E V I E W : Ring, Simon J.; Henehan, Michael J.; Blukis, Roberts; von Blanckenburg, Friedhelm (2024): Experimental adsorption parameters of boron isotopes on clay minerals. GFZ Data Services. https://doi.org/10.5880/GFZ.3.3.2024.003

Abstract

Adsorption and isotopic fractionation of boron on clastic sediment is one process responsible for the heavy boron isotopic composition of the modern ocean. However, the mechanism by which boron complexes to the surface of clay minerals and the cause of its isotopic fractionation are still unclear. We performed two sets of experiments, using solutions of pure water with added boron and seawater, to explore the isotope behavior during adsorption of boron onto kaolinite, smectite and illite. The dataset consists of an excel file with four sheets that store (1) the NIST RM 803 measurements we used to establish the long-term reproducibility of our isotope measurements, (2) results of our pure experiment, (3) results of our seawater experiments and (4) a global compilation of XRD-based riverine clay mineral assemblages.

Authors

Ring, Simon J.;GFZ German Research Centre for Geosciences, Potsdam, Germany;Institute of Geological Sciences, Freie Universität Berlin, Berlin, Germany
Henehan, Michael J.;GFZ German Research Centre for Geosciences, Potsdam, Germany;School of Earth Sciences, University of Bristol, Bristol, United Kingdom
Blukis, Roberts;Leibniz-Institut für Kristallzüchtung (IKZ), Berlin, Germany
von Blanckenburg, Friedhelm;GFZ German Research Centre for Geosciences, Potsdam, Germany;Institute of Geological Sciences, Freie Universität Berlin, Berlin, Germany

Contact

Ring, Simon J. (PhD student); GFZ German Research Centre for Geosciences, Potsdam, Germany;

Contributors

HELGES – Helmholtz-Laboratory for the Geochemistry of the Earth Surface

Funders

Deutsche Forschungsgemeinschaft (455982777)

Keywords

surface complexation model, clay, boron isotopes, boron adsorption, compound material > sedimentary material > sediment > clastic sediment > mud > clay, physicochemical process > sorption > adsorption, The Present

GCMD Science Keywords

EARTH SCIENCE > LAND SURFACE > EROSION/SEDIMENTATION > SUSPENDED SOLIDS
EARTH SCIENCE > TERRESTRIAL HYDROSPHERE > SURFACE WATER > SURFACE WATER CHEMISTRY
In Situ/Laboratory Instruments > Spectrometers/Radiometers > MC-ICP-MS

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