Released
Dataset

Soil and spring water gas data from an area with natural hydrogen (H2) degassing, NW Pyrenean foreland, France

Cite as:

Zwaan, Frank; Pilz, Peter; Niedermann, Samuel; Zimmer, Martin; Lefeuvre, Nicolas; Petit, Valentin; Vieth-Hillebrand, Andrea; Gaucher, Eric C.; Schmidt-Hattenberger, Cornelia; Brune, Sascha (2024): Soil and spring water gas data from an area with natural hydrogen (H2) degassing, NW Pyrenean foreland, France. GFZ Data Services. https://doi.org/10.5880/GFZ.2.5.2024.001

Status

I   N       R   E   V   I   E   W : Zwaan, Frank; Pilz, Peter; Niedermann, Samuel; Zimmer, Martin; Lefeuvre, Nicolas; Petit, Valentin; Vieth-Hillebrand, Andrea; Gaucher, Eric C.; Schmidt-Hattenberger, Cornelia; Brune, Sascha (2024): Soil and spring water gas data from an area with natural hydrogen (H2) degassing, NW Pyrenean foreland, France. GFZ Data Services. https://doi.org/10.5880/GFZ.2.5.2024.001

Abstract

This data set contains the results from a 2023 GFZ Innovative Research Expedition project to explore for natural hydrogen gas (H2) occurrences in the NW Pyrenean foreland, near the town of Biarritz in France. The data represent in-situ measurements of soil and spring water gas, as well as in-situ spring water property measurements, complemented with laboratory analysis results of gas contents and noble gas isotopic compositions of gas and spring water samples collected during the expedition.

This GFZ Innovative Research Expedition was inspired by previous exploration efforts in the region by Lefeuvre et al. (2021, 2022). These authors detected elevated concentrations of natural H2 gas in the soil and interpreted this natural H2 to be derived from serpentinizing mantle rocks below the Pyrenees.

The main aims of this expedition were the following: (1) in-situ measuring soil gas contents and taking soil gas samples for laboratory analysis at a site near the town of Peyrehorade in the NW of the general study area of Lefeuvre et al. (2021), thus improving the soil gas data coverage along the NW end of the North Pyrenean Frontal Thrust (NPFT); (2) taking gas samples from degassing springs (or water samples from non-degassing springs to be degassed in the lab) in the general Lefeuvre et al. (2021) study area for additional laboratory analysis of gas contents and noble gas isotopic compositions, which may be indicative of (deep) gas origins; and (3) performing a detailed soil gas analysis by means of a portable mass spectrometer at Sauveterre-de-Béarn, a site along the NPFT where Lefeuvre et al. (2022) measured elevated concentrations of natural H2 in the soil. Furthermore, we also measured the properties of the visited springs (temperature, pH, conductivity) while on site, and performed additional in-situ soil gas measurements from manual drillholes.

Details on the measurement and sampling methods, on the laboratory analyses, as well as the results of these measurements and analyses are provided in the data description file

The expedition involved six field days in July 2023, during which a total of 26 sites were visited. These sites were selected for their vicinity near a major geological contact or fault zone that could have facilitated upward circulation of gas or (thermal) water from the (deep) subsurface (i.e., potentially from the mantle).

Authors

  • Zwaan, Frank;GFZ German Research Centre for Geosciences, Potsdam, Germany;University of Fribourg, Department of Geosciences, Fribourg, Switzerland
  • Pilz, Peter;GFZ German Research Centre for Geosciences, Potsdam, Germany
  • Niedermann, Samuel;GFZ German Research Centre for Geosciences, Potsdam, Germany
  • Zimmer, Martin;GFZ German Research Centre for Geosciences, Potsdam, Germany
  • Lefeuvre, Nicolas;CVA Group, Pau, France
  • Petit, Valentin;CVA Group, Pau, France;University of Pau et des Pays de l’Adour, Pau, France
  • Vieth-Hillebrand, Andrea;GFZ German Research Centre for Geosciences, Potsdam, Germany
  • Gaucher, Eric C.;Lavoisier H2 Geoconsult, Chamonix, France
  • Schmidt-Hattenberger, Cornelia;GFZ German Research Centre for Geosciences, Potsdam, Germany
  • Brune, Sascha;GFZ German Research Centre for Geosciences, Potsdam, Germany;University of Potsdam, Potsdam, Germany

Contact

  • Zwaan, Frank (Postdoc Researcher); GFZ German Research Centre for Geosciences, Potsdam, Germany;

Contributors

Geochemistry Laboratories (GFZ German Research Centre for Geosciences, Germany); Laboratory for Compound-specific Isotope Analysis (GFZ German Research Centre for Geosciences, Germany); Noble Gas Lab (GFZ German Research Centre for Geosciences, Germany)

    Funders

  • Helmholtz-Zentrum Potsdam - Deutsches GeoForschungsZentrum GFZ: GFZ Innovative Research Expedition 2023
  • Helmholtz-Zentrum Potsdam - Deutsches GeoForschungsZentrum GFZ: GFZ Discovery Fund fellowship
  • CVA Group, Pau, France
  • University of Pau et des Pays de l’Adour, Pau, France

Keywords

GCMD Science Keywords

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            • CharacterString: This data set contains the results from a 2023 GFZ Innovative Research Expedition project to explore for natural hydrogen gas (H2) occurrences in the NW Pyrenean foreland, near the town of Biarritz in France. The data represent in-situ measurements of soil and spring water gas, as well as in-situ spring water property measurements, complemented with laboratory analysis results of gas contents and noble gas isotopic compositions of gas and spring water samples collected during the expedition. This GFZ Innovative Research Expedition was inspired by previous exploration efforts in the region by Lefeuvre et al. (2021, 2022). These authors detected elevated concentrations of natural H2 gas in the soil and interpreted this natural H2 to be derived from serpentinizing mantle rocks below the Pyrenees. The main aims of this expedition were the following: (1) in-situ measuring soil gas contents and taking soil gas samples for laboratory analysis at a site near the town of Peyrehorade in the NW of the general study area of Lefeuvre et al. (2021), thus improving the soil gas data coverage along the NW end of the North Pyrenean Frontal Thrust (NPFT); (2) taking gas samples from degassing springs (or water samples from non-degassing springs to be degassed in the lab) in the general Lefeuvre et al. (2021) study area for additional laboratory analysis of gas contents and noble gas isotopic compositions, which may be indicative of (deep) gas origins; and (3) performing a detailed soil gas analysis by means of a portable mass spectrometer at Sauveterre-de-Béarn, a site along the NPFT where Lefeuvre et al. (2022) measured elevated concentrations of natural H2 in the soil. Furthermore, we also measured the properties of the visited springs (temperature, pH, conductivity) while on site, and performed additional in-situ soil gas measurements from manual drillholes. Details on the measurement and sampling methods, on the laboratory analyses, as well as the results of these measurements and analyses are provided in the data description file The expedition involved six field days in July 2023, during which a total of 26 sites were visited. These sites were selected for their vicinity near a major geological contact or fault zone that could have facilitated upward circulation of gas or (thermal) water from the (deep) subsurface (i.e., potentially from the mantle).
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                • CharacterString: Postdoc Researcher
              • contactInfo
                • CI_Contact
                  • address
                    • CI_Address
                      • electronicMailAddress
                        • CharacterString: frank.zwaan(_at_)gfz-potsdam.de
                  • onlineResource
                    • CI_OnlineResource
                      • linkage
                        • URL: https://www.gfz-potsdam.de/staff/frank.zwaan
                      • function
                        • CI_OnLineFunctionCode (codeList=http://www.isotc211.org/2005/resources/Codelist/gmxCodelists.xml#CI_OnLineFunctionCode codeListValue=http://www.isotc211.org/2005/resources/Codelist/gmxCodelists.xml#CI_OnLineFunctionCode_information): informtion
              • role
                • CI_RoleCode (codeList=http://www.isotc211.org/2005/resources/Codelist/gmxCodelists.xml#CI_RoleCode codeListValue=pointOfContact): pointOfContact
          • descriptiveKeywords
            • MD_Keywords
              • keyword
                • CharacterString: 
          • descriptiveKeywords
            • MD_Keywords
              • keyword
                • CharacterString: EARTH SCIENCE > HUMAN DIMENSIONS > SUSTAINABILITY > SUSTAINABLE DEVELOPMENT
              • keyword
                • CharacterString: EARTH SCIENCE > SOLID EARTH > EARTH GASES/LIQUIDS > HYDROGEN GAS
              • keyword
                • CharacterString: EARTH SCIENCE > SOLID EARTH > EARTH GASES/LIQUIDS > HYDROGEN GAS > HYDROGEN GAS VERTICAL/GEOGRAPHIC DISTRIBUTION
              • keyword
                • CharacterString: EARTH SCIENCE > SOLID EARTH > GEOCHEMISTRY > GEOCHEMICAL PROPERTIES > CHEMICAL CONCENTRATIONS
              • keyword
                • CharacterString: EARTH SCIENCE > SOLID EARTH > GEOCHEMISTRY > GEOCHEMICAL PROPERTIES > ISOTOPE MEASUREMENTS
              • keyword
                • CharacterString: EARTH SCIENCE > SOLID EARTH > GEOCHEMISTRY > GEOCHEMICAL PROPERTIES > ISOTOPE RATIOS
              • keyword
                • CharacterString: EARTH SCIENCE > SOLID EARTH > GEOCHEMISTRY > GEOCHEMICAL PROPERTIES > ISOTOPES
              • keyword
                • CharacterString: EARTH SCIENCE > TERRESTRIAL HYDROSPHERE > WATER QUALITY/WATER CHEMISTRY > CARBON DIOXIDE
              • keyword
                • CharacterString: EARTH SCIENCE > TERRESTRIAL HYDROSPHERE > WATER QUALITY/WATER CHEMISTRY > CONDUCTIVITY
              • keyword
                • CharacterString: EARTH SCIENCE > TERRESTRIAL HYDROSPHERE > WATER QUALITY/WATER CHEMISTRY > DISSOLVED GASES
              • keyword
                • CharacterString: EARTH SCIENCE > TERRESTRIAL HYDROSPHERE > WATER QUALITY/WATER CHEMISTRY > PH
              • keyword
                • CharacterString: EARTH SCIENCE > TERRESTRIAL HYDROSPHERE > WATER QUALITY/WATER CHEMISTRY > WATER TEMPERATURE
              • thesaurusName
                • CI_Citation
                  • title
                    • CharacterString: NASA/GCMD Earth Science Keywords
                  • date
                    • CI_Date
                      • date (gco:nilReason=missing): 
                      • dateType
                        • CI_DateTypeCode (codeList=http://www.isotc211.org/2005/resources/Codelist/gmxCodelists.xml#CI_DateTypeCode codeListValue=publication): publication
          • descriptiveKeywords
            • MD_Keywords
              • keyword
                • CharacterString: In Situ Land-based Platforms > FIELD INVESTIGATION
              • keyword
                • CharacterString: In Situ Land-based Platforms > FIELD SURVEYS
              • keyword
                • CharacterString: In Situ Land-based Platforms > LABORATORY
              • keyword
                • CharacterString: Maps/Charts/Photographs > MAPS
              • thesaurusName
                • CI_Citation
                  • title
                    • CharacterString: GCMD Platforms
                  • date
                    • CI_Date
                      • date (gco:nilReason=missing): 
                      • dateType
                        • CI_DateTypeCode (codeList=http://www.isotc211.org/2005/resources/Codelist/gmxCodelists.xml#CI_DateTypeCode codeListValue=publication): publication
          • resourceConstraints (xlink:href=http://creativecommons.org/licenses/by/4.0/)
            • MD_Constraints
              • useLimitation
                • CharacterString: CC BY 4.0
          • resourceConstraints
            • MD_LegalConstraints
              • accessConstraints
                • MD_RestrictionCode (codeList=http://www.isotc211.org/2005/resources/codeList.xml#MD_RestrictionCode codeListValue=otherRestrictions): 
              • otherConstraints
                • CharacterString: CC BY 4.0
          • resourceConstraints
            • MD_SecurityConstraints
              • classification
                • MD_ClassificationCode (codeList=http://www.isotc211.org/2005/resources/codeList.xml#MD_ClassificationCode codeListValue=unclassified): 
          • aggregationInfo
            • MD_AggregateInformation
              • aggregateDataSetIdentifier
                • RS_Identifier
                  • code
                    • CharacterString: 10.1029/2021GC009917
                  • codeSpace
                    • CharacterString: DOI
              • associationType
                • DS_AssociationTypeCode (codeList=http://datacite.org/schema/kernel-4 codeListValue=Cites): Cites
          • aggregationInfo
            • MD_AggregateInformation
              • aggregateDataSetIdentifier
                • RS_Identifier
                  • code
                    • CharacterString: 10.1016/j.apgeochem.2022.105396
                  • codeSpace
                    • CharacterString: DOI
              • associationType
                • DS_AssociationTypeCode (codeList=http://datacite.org/schema/kernel-4 codeListValue=Cites): Cites
          • aggregationInfo
            • MD_AggregateInformation
              • aggregateDataSetIdentifier
                • RS_Identifier
                  • code
                    • CharacterString: 10.1016/S0016-7037(97)00102-6
                  • codeSpace
                    • CharacterString: DOI
              • associationType
                • DS_AssociationTypeCode (codeList=http://datacite.org/schema/kernel-4 codeListValue=Cites): Cites
          • language
            • CharacterString: eng
          • characterSet
            • MD_CharacterSetCode (codeListValue=utf8 codeList=http://www.isotc211.org/2005/resources/codeList.xml#MD_CharacterSetCode): 
          • topicCategory
            • MD_TopicCategoryCode: geoscientificInformation
          • extent
            • EX_Extent
              • description
                • CharacterString: Study site in the Pyrenees
              • geographicElement
                • EX_GeographicBoundingBox
                  • westBoundLongitude
                    • Decimal: -1.6
                  • eastBoundLongitude
                    • Decimal: -0.4
                  • southBoundLatitude
                    • Decimal: 43
                  • northBoundLatitude
                    • Decimal: 43.9
      • distributionInfo
        • MD_Distribution
          • transferOptions
            • MD_DigitalTransferOptions
              • onLine
                • CI_OnlineResource
                  • linkage
                    • URL: http://doi.org/10.5880/GFZ.2.5.2024.001
                  • protocol
                    • CharacterString: WWW:LINK-1.0-http--link
                  • name
                    • CharacterString: Data Access - DOI
                  • description
                    • CharacterString: Data Access - DOI
                  • function
                    • CI_OnLineFunctionCode (codeList=http://www.isotc211.org/2005/resources/Codelist/gmxCodelists.xml#CI_OnLineFunctionCode codeListValue=http://www.isotc211.org/2005/resources/Codelist/gmxCodelists.xml#CI_OnLineFunctionCode_information): information
      • dataQualityInfo
        • DQ_DataQuality
          • scope
            • DQ_Scope
              • level
                • MD_ScopeCode (codeListValue=dataset codeList=http://www.isotc211.org/2005/resources/codeList.xml#MD_ScopeCode): 
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