Released
Dataset

A database of the elemental and isotopic composition of water and carbonates from a hypersaline Andean lake (Laguna del Peinado, Argentina)

Cite as:

Vignoni, Paula Andrea; Jurikova, Hana; Schröder, Birgit; Tjallingii, Rik; Córdoba, Francisco Elizalde; Liebetrau, Volker; Lecomte, Karina Leticia; Pinkerneil, Sylvia; Grudzinska, Ieva; Schleicher, Anja M.; Viotto , Sofía Alejandra; Santamans, Carla; Rae, James W. B.; Brauer, Achim (2023): A database of the elemental and isotopic composition of water and carbonates from a hypersaline Andean lake (Laguna del Peinado, Argentina). GFZ Data Services. https://doi.org/10.5880/GFZ.4.3.2023.004

Status

I   N       R   E   V   I   E   W : Vignoni, Paula Andrea; Jurikova, Hana; Schröder, Birgit; Tjallingii, Rik; Córdoba, Francisco Elizalde; Liebetrau, Volker; Lecomte, Karina Leticia; Pinkerneil, Sylvia; Grudzinska, Ieva; Schleicher, Anja M.; Viotto , Sofía Alejandra; Santamans, Carla; Rae, James W. B.; Brauer, Achim (2023): A database of the elemental and isotopic composition of water and carbonates from a hypersaline Andean lake (Laguna del Peinado, Argentina). GFZ Data Services. https://doi.org/10.5880/GFZ.4.3.2023.004

Abstract

The dataset presented here encompasses the results of the geochemical analyses of water and recent carbonate samples collected in the El Peinado basin located in the Southern Puna Plateau in Catamarca, Argentina. This system formed by the hypersaline lake Laguna del Peinado, numerous hydrothermal springs, and the small hypersaline lake Laguna Turquesa, provides a natural laboratory to study carbonate formation and the mechanisms that control the incorporation of various elements and isotopes into their structure under a broad range of geochemical conditions. Geochemical analyses include data on the physicochemical parameters, elemental, and isotopic (δ18O, δ2H, δ11B) composition of the waters, and data on the elemental and isotopic (δ18O, δ13C, δ11B) composition of the carbonates. These data allowed us to calculate element partition coefficients and isotopic fractionation between coupled water-carbonate samples from this natural setting, which are also included here. This dataset also includes the results of water modelling using the software PHREEQC, which contains data on the chemical speciation of carbon and boron, the species contributing to total alkalinity, and mineral saturation indices. This information is useful for all those dealing with geochemistry of hypersaline lakes, geochemistry of continental carbonates, as well as paleoenvironmental and paleoclimatic studies using lake carbonates as archives. These data correspond to the research article “On the origin and processes controlling the elemental and isotopic composition of carbonates in hypersaline Andean lakes”. The full description of the data is provided in the data description file.

Methods

Sampling method

During fieldwork in January 2019, November 2019 and February 2021 (austral spring-summer), water samples were collected for isotopic and elemental analyses from the main water body Laguna del Peinado, the smaller Laguna Turquesa, the inflowing hydrothermal springs, and the wetlands. Rainwater was sampled in the nearest town, Antofagasta de la Sierra (3320 m a.s.l.) approximately 80 km to the NE and snow was collected at nearly 5000 m a.s.l., 17 km SE of the lake. For elemental analyses, water samples were filtered and an aliquot was acidified for metals determinations.

Short sediment cores (< 1 m) were recovered from Laguna del Peinado using a raft equipped with an Uwitec coring device. Carbonate and surface sediment samples were collected from the lakes, hot springs, and catchment area, packed in polyethylene vials and plastic bags, and stored at 4°C.


Authors

  • Vignoni, Paula Andrea;Institute of Geosciences, University of Potsdam, Potsdam, Germany;GFZ German Research Centre for Geosciences, Potsdam, Germany
  • Jurikova, Hana;GFZ German Research Centre for Geosciences, Potsdam, Germany;School of Earth and Environmental Sciences, University of St Andrews, United Kingdom
  • Schröder, Birgit;GFZ German Research Centre for Geosciences, Potsdam, Germany
  • Tjallingii, Rik;GFZ German Research Centre for Geosciences, Potsdam, Germany
  • Córdoba, Francisco Elizalde;Instituto de Ecorregiones Andinas INECOA, CONICET – Universidad Nacional de Jujuy, Jujuy, Argentina;Instituto de Geología y Minería, Universidad Nacional de Jujuy, Jujuy, Argentina
  • Liebetrau, Volker;GEOMAR Helmholtz Centre for Ocean Research Kiel, Kiel, Germany
  • Lecomte, Karina Leticia;Centro de Investigaciones de Ciencias de la Tierra, CONICET – Universidad Nacional de Córdoba, Córdoba, Argentina
  • Pinkerneil, Sylvia;GFZ German Research Centre for Geosciences, Potsdam, Germany
  • Grudzinska, Ieva;Geoecology group, Department of Environmental Sciences, University of Basel, Basel, Switzerland;Institute of Biology, University of Latvia, Riga, Latvia
  • Schleicher, Anja M.;GFZ German Research Centre for Geosciences, Potsdam, Germany
  • Viotto , Sofía Alejandra;Institute of Geosciences, University of Potsdam, Potsdam, Germany
  • Santamans, Carla;Instituto de Ecorregiones Andinas INECOA, CONICET – Universidad Nacional de Jujuy, Jujuy, Argentina;Instituto de Geología y Minería, Universidad Nacional de Jujuy, Jujuy, Argentina
  • Rae, James W. B.;School of Earth and Environmental Sciences, University of St Andrews, United Kingdom
  • Brauer, Achim;Institute of Geosciences, University of Potsdam, Potsdam, Germany;GFZ German Research Centre for Geosciences, Potsdam, Germany

Contact

  • Vignoni, Paula Andrea (PhD student); Climate dynamics and landscape evolution, GFZ German Research Centre for Geosciences, Potsdam, Germany;

Contributors

Ion Chromatography (GFZ German Research Centre for Geosciences)

    Funders

  • Deutsche Forschungsgemeinschaft: STRATEGy: “SuRfAce processes, TEctonics and Georesources: The Andean foreland basin of Argentina”  (373/34-1)  
  • Helmholtz-Zentrum Potsdam - Deutsches GeoForschungsZentrum GFZ

Keywords

lacustrine carbonates, evaporitic enrichment, brine-carbonate chemistry, boron isotopes, partitioning coefficients, isotopic fractionation, hot springs, Altiplano-Puna Plateau, compound material > sedimentary material > carbonate sedimentary material, physical process > evaporation

GCMD Science Keywords

More Metadata

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          • affiliation: GFZ German Research Centre for Geosciences, Potsdam, Germany
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          • givenName: Hana
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          • affiliation: School of Earth and Environmental Sciences, University of St Andrews, United Kingdom
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          • givenName: Francisco Elizalde
          • familyName: Córdoba
          • affiliation: Instituto de Ecorregiones Andinas INECOA, CONICET – Universidad Nacional de Jujuy, Jujuy, Argentina
          • affiliation: Instituto de Geología y Minería, Universidad Nacional de Jujuy, Jujuy, Argentina
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          • familyName: Lecomte
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          • affiliation: Centro de Investigaciones de Ciencias de la Tierra, CONICET – Universidad Nacional de Córdoba, Córdoba, Argentina
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          • affiliation: Geoecology group, Department of Environmental Sciences, University of Basel, Basel, Switzerland
          • affiliation: Institute of Biology, University of Latvia, Riga, Latvia
        • creator
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          • familyName: Schleicher
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          • affiliation: GFZ German Research Centre for Geosciences, Potsdam, Germany
        • creator
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          • givenName: Sofía Alejandra
          • familyName: Viotto
          • nameIdentifier (nameIdentifierScheme=ORCID): 0000-0001-7977-2473
          • affiliation: Institute of Geosciences, University of Potsdam, Potsdam, Germany
        • creator
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          • givenName: Carla
          • familyName: Santamans
          • nameIdentifier (nameIdentifierScheme=ORCID): 0000-0003-4353-5956
          • affiliation: Instituto de Ecorregiones Andinas INECOA, CONICET – Universidad Nacional de Jujuy, Jujuy, Argentina
          • affiliation: Instituto de Geología y Minería, Universidad Nacional de Jujuy, Jujuy, Argentina
        • creator
          • creatorName (nameType=Personal): Rae, James W. B.
          • givenName: James W. B.
          • familyName: Rae
          • nameIdentifier (nameIdentifierScheme=ORCID): 0000-0003-3904-2526
          • affiliation: School of Earth and Environmental Sciences, University of St Andrews, United Kingdom
        • creator
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          • givenName: Achim
          • familyName: Brauer
          • nameIdentifier (nameIdentifierScheme=ORCID): 0000-0002-6655-9451
          • affiliation: Institute of Geosciences, University of Potsdam, Potsdam, Germany
          • affiliation: GFZ German Research Centre for Geosciences, Potsdam, Germany
      • titles
        • title: A database of the elemental and isotopic composition of water and carbonates from a hypersaline Andean lake (Laguna del Peinado, Argentina)
      • publisher: GFZ Data Services
      • publicationYear: 2023
      • subjects
        • subject: lacustrine carbonates
        • subject: evaporitic enrichment
        • subject: brine-carbonate chemistry
        • subject: boron isotopes
        • subject: partitioning coefficients
        • subject: isotopic fractionation
        • subject: hot springs
        • subject: Altiplano-Puna Plateau
        • subject (subjectScheme=CGI Simple Lithology): compound material > sedimentary material > carbonate sedimentary material
        • subject (subjectScheme=NASA/GCMD Earth Science Keywords): EARTH SCIENCE > TERRESTRIAL HYDROSPHERE > GROUND WATER > SPRINGS
        • subject (subjectScheme=NASA/GCMD Earth Science Keywords): EARTH SCIENCE > TERRESTRIAL HYDROSPHERE > SURFACE WATER > LAKES
        • subject (subjectScheme=NASA/GCMD Earth Science Keywords): EARTH SCIENCE > TERRESTRIAL HYDROSPHERE > SURFACE WATER > SURFACE WATER CHEMISTRY
        • subject (subjectScheme=GEMET - INSPIRE themes, version 1.0): physical process > evaporation
      • contributors
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          • givenName: Paula Andrea
          • familyName: Vignoni
          • nameIdentifier (nameIdentifierScheme=ORCID): 0000-0002-9681-4986
          • affiliation: Institute of Geosciences, University of Potsdam, Potsdam, Germany
          • affiliation: GFZ German Research Centre for Geosciences, Potsdam, Germany
        • contributor (contributorType=DataCollector)
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          • familyName: Vignoni
          • nameIdentifier (nameIdentifierScheme=ORCID): 0000-0002-9681-4986
          • affiliation: Institute of Geosciences, University of Potsdam, Potsdam, Germany
          • affiliation: GFZ German Research Centre for Geosciences, Potsdam, Germany
        • contributor (contributorType=DataCollector)
          • contributorName (nameType=Personal): Jurikova, Hana
          • givenName: Hana
          • familyName: Jurikova
          • affiliation: GFZ German Research Centre for Geosciences, Potsdam, Germany
          • affiliation: School of Earth and Environmental Sciences, University of St Andrews, United Kingdom
        • contributor (contributorType=DataCollector)
          • contributorName (nameType=Personal): Schröder, Birgit
          • givenName: Birgit
          • familyName: Schröder
          • nameIdentifier (nameIdentifierScheme=ORCID): 0000-0003-4807-6357
          • affiliation: GFZ German Research Centre for Geosciences, Potsdam, Germany
        • contributor (contributorType=Supervisor)
          • contributorName (nameType=Personal): Tjallingii, Rik
          • givenName: Rik
          • familyName: Tjallingii
          • nameIdentifier (nameIdentifierScheme=ORCID): 0000-0002-9723-3622
          • affiliation: GFZ German Research Centre for Geosciences, Potsdam, Germany
        • contributor (contributorType=DataCollector)
          • contributorName (nameType=Personal): Córdoba, Francisco Elizalde
          • givenName: Francisco Elizalde
          • familyName: Córdoba
          • affiliation: Instituto de Ecorregiones Andinas INECOA, CONICET – Universidad Nacional de Jujuy, Jujuy, Argentina
          • affiliation: Instituto de Geología y Minería, Universidad Nacional de Jujuy, Jujuy, Argentina
        • contributor (contributorType=Supervisor)
          • contributorName (nameType=Personal): Córdoba, Francisco Elizalde
          • givenName: Francisco Elizalde
          • familyName: Córdoba
          • affiliation: Instituto de Ecorregiones Andinas INECOA, CONICET – Universidad Nacional de Jujuy, Jujuy, Argentina
          • affiliation: Instituto de Geología y Minería, Universidad Nacional de Jujuy, Jujuy, Argentina
        • contributor (contributorType=DataCollector)
          • contributorName (nameType=Personal): Liebetrau, Volker
          • givenName: Volker
          • familyName: Liebetrau
          • affiliation: GEOMAR Helmholtz Centre for Ocean Research Kiel, Kiel, Germany
        • contributor (contributorType=DataCollector)
          • contributorName (nameType=Personal): Lecomte, Karina Leticia
          • givenName: Karina Leticia
          • familyName: Lecomte
          • nameIdentifier (nameIdentifierScheme=ORCID): 0000-0001-6901-0918
          • affiliation: Centro de Investigaciones de Ciencias de la Tierra, CONICET – Universidad Nacional de Córdoba, Córdoba, Argentina
        • contributor (contributorType=DataCollector)
          • contributorName (nameType=Personal): Pinkerneil, Sylvia
          • givenName: Sylvia
          • familyName: Pinkerneil
          • affiliation: GFZ German Research Centre for Geosciences, Potsdam, Germany
        • contributor (contributorType=Researcher)
          • contributorName (nameType=Personal): Grudzinska, Ieva
          • givenName: Ieva
          • familyName: Grudzinska
          • nameIdentifier (nameIdentifierScheme=ORCID): 0000-0003-0722-515X
          • affiliation: Geoecology group, Department of Environmental Sciences, University of Basel, Basel, Switzerland
          • affiliation: Institute of Biology, University of Latvia, Riga, Latvia
        • contributor (contributorType=DataCollector)
          • contributorName (nameType=Personal): Schleicher, Anja M.
          • givenName: Anja M.
          • familyName: Schleicher
          • nameIdentifier (nameIdentifierScheme=ORCID): 0000-0003-4052-8654
          • affiliation: GFZ German Research Centre for Geosciences, Potsdam, Germany
        • contributor (contributorType=Researcher)
          • contributorName (nameType=Personal): Viotto , Sofía Alejandra
          • givenName: Sofía Alejandra
          • familyName: Viotto
          • nameIdentifier (nameIdentifierScheme=ORCID): 0000-0001-7977-2473
          • affiliation: Institute of Geosciences, University of Potsdam, Potsdam, Germany
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          • givenName: Carla
          • familyName: Santamans
          • nameIdentifier (nameIdentifierScheme=ORCID): 0000-0003-4353-5956
          • affiliation: Instituto de Ecorregiones Andinas INECOA, CONICET – Universidad Nacional de Jujuy, Jujuy, Argentina
          • affiliation: Instituto de Geología y Minería, Universidad Nacional de Jujuy, Jujuy, Argentina
        • contributor (contributorType=Researcher)
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          • givenName: James W. B.
          • familyName: Rae
          • nameIdentifier (nameIdentifierScheme=ORCID): 0000-0003-3904-2526
          • affiliation: School of Earth and Environmental Sciences, University of St Andrews, United Kingdom
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          • givenName: Achim
          • familyName: Brauer
          • nameIdentifier (nameIdentifierScheme=ORCID): 0000-0002-6655-9451
          • affiliation: Institute of Geosciences, University of Potsdam, Potsdam, Germany
          • affiliation: GFZ German Research Centre for Geosciences, Potsdam, Germany
        • contributor (contributorType=Supervisor)
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          • givenName: Achim
          • familyName: Brauer
          • nameIdentifier (nameIdentifierScheme=ORCID): 0000-0002-6655-9451
          • affiliation: Institute of Geosciences, University of Potsdam, Potsdam, Germany
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          • affiliation: GFZ German Research Centre for Geosciences, Potsdam, Germany
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          • affiliation: Climate dynamics and landscape evolution, GFZ German Research Centre for Geosciences, Potsdam, Germany
      • dates
        • date (dateType=Created): 2021-07
        • date (dateType=Valid): 2019-01/2021-02
        • date (dateType=Collected): 2019/2021
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        • relatedIdentifier (relatedIdentifierType=DOI relationType=Cites): 10.2110/palo.2013.049
        • relatedIdentifier (relatedIdentifierType=DOI relationType=Cites): 10.5281/zenodo.7305148
        • relatedIdentifier (relatedIdentifierType=DOI relationType=Cites): 10.1007/978-3-319-19716-6
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        • relatedIdentifier (relatedIdentifierType=DOI relationType=Cites): 10.1016/j.gca.2020.03.020
        • relatedIdentifier (relatedIdentifierType=DOI relationType=Cites): 10.1016/j.epsl.2015.01.006
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        • relatedIdentifier (relatedIdentifierType=DOI relationType=Cites): 10.1016/S0012-821X(99)00150-8
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            • eastBoundLongitude: -68.0017
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          • awardTitle: STRATEGy: “SuRfAce processes, TEctonics and Georesources: The Andean foreland basin of Argentina”
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            • CharacterString: The dataset presented here encompasses the results of the geochemical analyses of water and recent carbonate samples collected in the El Peinado basin located in the Southern Puna Plateau in Catamarca, Argentina. This system formed by the hypersaline lake Laguna del Peinado, numerous hydrothermal springs, and the small hypersaline lake Laguna Turquesa, provides a natural laboratory to study carbonate formation and the mechanisms that control the incorporation of various elements and isotopes into their structure under a broad range of geochemical conditions. Geochemical analyses include data on the physicochemical parameters, elemental, and isotopic (δ18O, δ2H, δ11B) composition of the waters, and data on the elemental and isotopic (δ18O, δ13C, δ11B) composition of the carbonates. These data allowed us to calculate element partition coefficients and isotopic fractionation between coupled water-carbonate samples from this natural setting, which are also included here. This dataset also includes the results of water modelling using the software PHREEQC, which contains data on the chemical speciation of carbon and boron, the species contributing to total alkalinity, and mineral saturation indices. This information is useful for all those dealing with geochemistry of hypersaline lakes, geochemistry of continental carbonates, as well as paleoenvironmental and paleoclimatic studies using lake carbonates as archives. These data correspond to the research article “On the origin and processes controlling the elemental and isotopic composition of carbonates in hypersaline Andean lakes”. The full description of the data is provided in the data description file.
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                        • CharacterString: pvignoni(_at_)gfz-potsdam.de; vignoni.paula@gmail.com
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                    • CharacterString: 10.1016/j.gca.2023.11.032
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                    • CharacterString: DOI
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                • CharacterString: This dataset includes analyses of samples collected between January 2019 and February 2021 in the El Peinado basin, Catamarca, Argentina.
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                    • Decimal: -68.187
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                      • endPosition: 2021
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                    • URL: http://doi.org/10.5880/GFZ.4.3.2023.004
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                • CharacterString: Sampling method During fieldwork in January 2019, November 2019 and February 2021 (austral spring-summer), water samples were collected for isotopic and elemental analyses from the main water body Laguna del Peinado, the smaller Laguna Turquesa, the inflowing hydrothermal springs, and the wetlands. Rainwater was sampled in the nearest town, Antofagasta de la Sierra (3320 m a.s.l.) approximately 80 km to the NE and snow was collected at nearly 5000 m a.s.l., 17 km SE of the lake. For elemental analyses, water samples were filtered and an aliquot was acidified for metals determinations. Short sediment cores (< 1 m) were recovered from Laguna del Peinado using a raft equipped with an Uwitec coring device. Carbonate and surface sediment samples were collected from the lakes, hot springs, and catchment area, packed in polyethylene vials and plastic bags, and stored at 4°C.
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    License: CC BY 4.0

    Dataset Description

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