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Accessory Minerals in Felsic Igneous Rocks - Part 4: Composition of allanite-(Ce), monazite-(Ce), xenotime-(Y) and zircon from the multi-stage, weakly peraluminous F-poor granite massifs of Kirchberg and Niederbobritzsch (Erzgebirge−Vogtland metallogenic province, Germany)

Cite as:

Förster, Hans-Jürgen (2019): Accessory Minerals in Felsic Igneous Rocks - Part 4: Composition of allanite-(Ce), monazite-(Ce), xenotime-(Y) and zircon from the multi-stage, weakly peraluminous F-poor granite massifs of Kirchberg and Niederbobritzsch (Erzgebirge−Vogtland metallogenic province, Germany). GFZ Data Services. https://doi.org/10.5880/GFZ.4.8.2019.001

Status

I   N       R   E   V   I   E   W : Förster, Hans-Jürgen (2019): Accessory Minerals in Felsic Igneous Rocks - Part 4: Composition of allanite-(Ce), monazite-(Ce), xenotime-(Y) and zircon from the multi-stage, weakly peraluminous F-poor granite massifs of Kirchberg and Niederbobritzsch (Erzgebirge−Vogtland metallogenic province, Germany). GFZ Data Services. https://doi.org/10.5880/GFZ.4.8.2019.001

Abstract

This data set is the 4th contribution of a series reporting chemical data for accessory minerals from felsic igneous rocks. It deals with two late Variscan biotite-granite massifs emplaced in the Saxothuringian Zone of the Variscan Orogen (Erzgebirge−Vogtland metallogenic province) in Germany. Mineral compositions were measured by electron-microprobe on surface rocks and borehole samples.


The data set assembles the results of electron-microprobe spot analyses of primary and secondary allanite-(Ce), monazite-(Ce), xenotime-(Y) and zircon from the multi-phase biotite-granite plutons of Kirchberg (KIB, Western Erzgebirge) and Niederbobritzsch (NBZ, Eastern Erzgebirge). Both plutons comprise several, compositionally and texturally distinct sub-intrusions, contain locally centimeter- to decimeter-sized co-genetic enclaves and xenoliths, and are cross-cut by chemically distinct, fine-grained aplitic dikes. These late-Variscan (c. 325 Ma) granites are moderately to highly evolved and (not considering enclaves) span the SiO2-range (in wt%) 67.0-77.4 (KIB) and 66.8-76.2 (NBZ). The granites are weakly peraluminous (A/CNK = 1.04−1.11 for KIB and 0.99-1.10 for NBZ) and of transitional I−S-type affinity.


Formation of primary allanite-(Ce) was restricted to the least-evolved subintrusions KIB1 and NBZ1 of both massifs. All other granites contain monazite-(Ce) as predominant LREE host. Magmatic allanite-(Ce) is variably altered and characterized by totals <100 wt%, implying the presence of several wt% water in the structure. Synchysite-(Ce) constitutes one of its alteration minerals. The Kirchberg massif hosts a second sub-facies of KIB1 that contains monazite instead of allanite as primary species. Severe alteration of this granite facies gave rise to partial or complete dissolution of part of the monazite accompanied by formation of allanite-epidote solid solutions as alteration product. Monazite-(Ce) displays large variations in Th versus REE concentrations even at thin-section scale. Incorporation of Th is mainly governed by the huttonite substitution Th^4+ + Si^4+ = REE^3+ + P^5+. Thorium concentrations span the range 1.33 – 41.8 wt.% ThO2. Xenotime-(Y) does not occur in KBI1 and NBZ1, but crystallized in all other subintrusions. Notable is the predominance of the heaviest REE Er-Lu (normalized to chondrite).


The data set contains the complete pile of electron-microprobe analyses for the four accessory minerals allanite-(Ce) (ALLA-KIB-NBZ2019), monazite-(Ce) (MONA-KIB-NBZ2019), xenotime-(Y) (XENO-KIB-NBZ2019) and zircon (ZIRC-KIB-NBZ2019). All tables are presented as Excel (xlsx) and machine-readable csv formats. The content of the tables and further data description are given in the data description file, together with BSE images of primary and secondary allanite-(Ce) from the KIB1 subintrusion.

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Contributors

Rhede, Dieter; Appelt, Oona

Keywords

monazite, xenotime, zircon, allanite, mineral composition, magma differentiation, electron-microprobe analysis, rare earth elements, Variscan orogeny, late Carboniferous, Erzgebirge-Vogtland, multi-phase biotite-granite plutons

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    License: CC BY 4.0