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Dataset

Sediment geochemistry data for the publication: “10Be/9Be ratios reveal marine authigenic clay formation”

Cite as:

Bernhardt, Anne; Oelze, Marcus; Bouchez, Julien; von Blanckenburg, Friedhelm; Mohtadi, Mahyar; Christl, Marcus; Wittmann-Oelze, Hella (2020): Sediment geochemistry data for the publication: “10Be/9Be ratios reveal marine authigenic clay formation”. GFZ Data Services. https://doi.org/10.5880/fidgeo.2020.009

Status

I   N       R   E   V   I   E   W : Bernhardt, Anne; Oelze, Marcus; Bouchez, Julien; von Blanckenburg, Friedhelm; Mohtadi, Mahyar; Christl, Marcus; Wittmann-Oelze, Hella (2020): Sediment geochemistry data for the publication: “10Be/9Be ratios reveal marine authigenic clay formation”. GFZ Data Services. https://doi.org/10.5880/fidgeo.2020.009

Abstract

As reverse weathering has been shown to impact long-term changes in atmospheric CO2 levels, it is crucial to develop quantitative tools to reconstruct marine authigenic clay formation. We explored the potential of the beryllium (Be) isotope ratio (10Be/9Be) recorded in marine clay-sized sediment to track neoformation of authigenic clays. The power of such proxy relies on the orders-of-magnitude difference in 10Be/9Be ratios between continental Be and Be dissolved in seawater. On riverine and marine sediments collected along a Chilean margin transect we chemically extracted reactive phases and separated the clay-sized sediment fraction. We compare the riverine and marine 10Be/9Be ratio of this fraction. Moreover, we compare the elemental and mineralogical composition and the Nd and Sr-isotopic composition of these samples. 10Be/9Be ratios increase four-fold from riverine to marine sediment. We attribute this increase to the incorporation of Be high in 10Be/9Be from dissolved biogenic opal, which also serves as a Si-source for the precipitation of marine authigenic clays. 10Be/9Be ratios thus sensitively track reverse-weathering reactions forming marine authigenic clays.

Authors

  • Bernhardt, Anne;Institute of Geological Sciences, Freie Universitaet Berlin, Berlin, Germany;Freie Universitaet Berlin, Berlin, Germany
  • Oelze, Marcus;GFZ German Research Centre for Geosciences, Inorganic and Isotope Geochemistry, Potsdam, Germany;GFZ German Research Centre for Geosciences, Potsdam, Germany
  • Bouchez, Julien;Institut de Physique du Globe de Paris, 1 rue Jussieu, 75238 Paris 05, France
  • von Blanckenburg, Friedhelm;GFZ German Research Centre for Geosciences, Earth Surface Geochemistry, Potsdam, Germany;GFZ German Research Centre for Geosciences, Potsdam, Germany
  • Mohtadi, Mahyar;MARUM Center for Marine Environmental Sciences, Bremen University, Bremen, Germany
  • Christl, Marcus;Laboratory of Ion Beam Physics, Department of Physics, ETH Zurich, Zurich, Switzerland;ETH Zurich, Zurich, Switzerland
  • Wittmann-Oelze, Hella;GFZ German Research Centre for Geosciences, Earth Surface Geochemistry, Potsdam, Germany;GFZ German Research Centre for Geosciences, Potsdam, Germany

Contact

  • Bernhardt, Anne (Prof.); Institute of Geological Sciences, Freie Universitaet Berlin, Berlin, Germany;

    Funders

  • Deutsche Forschungsgemeinschaft: Meteoric 10Be as a tracer of terrestrial denudation in marine sediments: A feasibility study offshore central Chile  (BE 5070/2-1)  
  • Deutsche Forschungsgemeinschaft: Meteoric 10Be as a tracer of terrestrial denudation in marine sediments: A feasibility study offshore central Chile  (WI 3874/2-1)  

Keywords

reverse weathering, authigenic clay, beryllium, cosmogenic nuclide, 10Be, denudation, compound material > sedimentary material > chemical sedimentary material, compound material > sedimentary material > clastic sedimentary material, compound material > sedimentary material > sediment, compound material > sedimentary material > sediment > mud size sediment, geological process > sedimentation (geology)

GCMD Science Keywords

More Metadata

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      • publisher: GFZ Data Services
      • publicationYear: 2020
      • subjects
        • subject: reverse weathering
        • subject: authigenic clay
        • subject: beryllium
        • subject: cosmogenic nuclide
        • subject: 10Be
        • subject: denudation
        • subject (subjectScheme=CGI Simple Lithology): compound material > sedimentary material > chemical sedimentary material
        • subject (subjectScheme=CGI Simple Lithology): compound material > sedimentary material > clastic sedimentary material
        • subject (subjectScheme=CGI Simple Lithology): compound material > sedimentary material > sediment
        • subject (subjectScheme=CGI Simple Lithology): compound material > sedimentary material > sediment > mud size sediment
        • subject (subjectScheme=NASA/GCMD Earth Science Keywords): EARTH SCIENCE > LAND SURFACE > EROSION/SEDIMENTATION > EROSION
        • subject (subjectScheme=NASA/GCMD Earth Science Keywords): EARTH SCIENCE > LAND SURFACE > EROSION/SEDIMENTATION > SEDIMENTS
        • subject (subjectScheme=NASA/GCMD Earth Science Keywords): EARTH SCIENCE > LAND SURFACE > EROSION/SEDIMENTATION > WEATHERING
        • subject (subjectScheme=NASA/GCMD Earth Science Keywords): EARTH SCIENCE > OCEANS > MARINE SEDIMENTS > PARTICLE FLUX
        • subject (subjectScheme=NASA/GCMD Earth Science Keywords): EARTH SCIENCE > OCEANS > MARINE SEDIMENTS > SEDIMENT CHEMISTRY
        • subject (subjectScheme=NASA/GCMD Earth Science Keywords): EARTH SCIENCE > OCEANS > MARINE SEDIMENTS > SEDIMENT COMPOSITION
        • subject (subjectScheme=NASA/GCMD Earth Science Keywords): EARTH SCIENCE > OCEANS > MARINE SEDIMENTS > TERRIGENOUS SEDIMENTS
        • subject (subjectScheme=NASA/GCMD Earth Science Keywords): EARTH SCIENCE > OCEANS > OCEAN CHEMISTRY > MARINE GEOCHEMISTRY
        • subject (subjectScheme=NASA/GCMD Earth Science Keywords): EARTH SCIENCE > OCEANS > OCEAN CHEMISTRY > RADIONUCLIDES
        • subject (subjectScheme=NASA/GCMD Earth Science Keywords): EARTH SCIENCE > SOLID EARTH > GEOCHEMISTRY > GEOCHEMICAL PROCESSES > CHEMICAL WEATHERING
        • subject (subjectScheme=NASA/GCMD Earth Science Keywords): EARTH SCIENCE > SOLID EARTH > GEOCHEMISTRY > GEOCHEMICAL PROPERTIES > CHEMICAL CONCENTRATIONS
        • subject (subjectScheme=NASA/GCMD Earth Science Keywords): EARTH SCIENCE > SOLID EARTH > GEOCHEMISTRY > GEOCHEMICAL PROPERTIES > ISOTOPE RATIOS
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            • CharacterString: As reverse weathering has been shown to impact long-term changes in atmospheric CO2 levels, it is crucial to develop quantitative tools to reconstruct marine authigenic clay formation. We explored the potential of the beryllium (Be) isotope ratio (10Be/9Be) recorded in marine clay-sized sediment to track neoformation of authigenic clays. The power of such proxy relies on the orders-of-magnitude difference in 10Be/9Be ratios between continental Be and Be dissolved in seawater. On riverine and marine sediments collected along a Chilean margin transect we chemically extracted reactive phases and separated the clay-sized sediment fraction. We compare the riverine and marine 10Be/9Be ratio of this fraction. Moreover, we compare the elemental and mineralogical composition and the Nd and Sr-isotopic composition of these samples. 10Be/9Be ratios increase four-fold from riverine to marine sediment. We attribute this increase to the incorporation of Be high in 10Be/9Be from dissolved biogenic opal, which also serves as a Si-source for the precipitation of marine authigenic clays. 10Be/9Be ratios thus sensitively track reverse-weathering reactions forming marine authigenic clays.
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                        • CI_OnLineFunctionCode (codeList=http://www.isotc211.org/2005/resources/Codelist/gmxCodelists.xml#CI_OnLineFunctionCode codeListValue=http://www.isotc211.org/2005/resources/Codelist/gmxCodelists.xml#CI_OnLineFunctionCode_information): informtion
              • role
                • CI_RoleCode (codeList=http://www.isotc211.org/2005/resources/Codelist/gmxCodelists.xml#CI_RoleCode codeListValue=pointOfContact): pointOfContact
          • descriptiveKeywords
            • MD_Keywords
              • keyword
                • CharacterString: reverse weathering
              • keyword
                • CharacterString: authigenic clay
              • keyword
                • CharacterString: beryllium
              • keyword
                • CharacterString: cosmogenic nuclide
              • keyword
                • CharacterString: 10Be
              • keyword
                • CharacterString: denudation
          • descriptiveKeywords
            • MD_Keywords
              • keyword
                • CharacterString: compound material > sedimentary material > chemical sedimentary material
              • keyword
                • CharacterString: compound material > sedimentary material > clastic sedimentary material
              • keyword
                • CharacterString: compound material > sedimentary material > sediment
              • keyword
                • CharacterString: compound material > sedimentary material > sediment > mud size sediment
              • thesaurusName
                • CI_Citation
                  • title
                    • CharacterString: CGI Simple Lithology
                  • date
                    • CI_Date
                      • date (gco:nilReason=missing): 
                      • dateType
                        • CI_DateTypeCode (codeList=http://www.isotc211.org/2005/resources/Codelist/gmxCodelists.xml#CI_DateTypeCode codeListValue=publication): publication
          • descriptiveKeywords
            • MD_Keywords
              • keyword
                • CharacterString: EARTH SCIENCE > LAND SURFACE > EROSION/SEDIMENTATION > EROSION
              • keyword
                • CharacterString: EARTH SCIENCE > LAND SURFACE > EROSION/SEDIMENTATION > SEDIMENTS
              • keyword
                • CharacterString: EARTH SCIENCE > LAND SURFACE > EROSION/SEDIMENTATION > WEATHERING
              • keyword
                • CharacterString: EARTH SCIENCE > OCEANS > MARINE SEDIMENTS > PARTICLE FLUX
              • keyword
                • CharacterString: EARTH SCIENCE > OCEANS > MARINE SEDIMENTS > SEDIMENT CHEMISTRY
              • keyword
                • CharacterString: EARTH SCIENCE > OCEANS > MARINE SEDIMENTS > SEDIMENT COMPOSITION
              • keyword
                • CharacterString: EARTH SCIENCE > OCEANS > MARINE SEDIMENTS > TERRIGENOUS SEDIMENTS
              • keyword
                • CharacterString: EARTH SCIENCE > OCEANS > OCEAN CHEMISTRY > MARINE GEOCHEMISTRY
              • keyword
                • CharacterString: EARTH SCIENCE > OCEANS > OCEAN CHEMISTRY > RADIONUCLIDES
              • keyword
                • CharacterString: EARTH SCIENCE > SOLID EARTH > GEOCHEMISTRY > GEOCHEMICAL PROCESSES > CHEMICAL WEATHERING
              • keyword
                • CharacterString: EARTH SCIENCE > SOLID EARTH > GEOCHEMISTRY > GEOCHEMICAL PROPERTIES > CHEMICAL CONCENTRATIONS
              • keyword
                • CharacterString: EARTH SCIENCE > SOLID EARTH > GEOCHEMISTRY > GEOCHEMICAL PROPERTIES > ISOTOPE RATIOS
              • keyword
                • CharacterString: EARTH SCIENCE > SOLID EARTH > GEOCHEMISTRY > GEOCHEMICAL PROPERTIES > ISOTOPES
              • keyword
                • CharacterString: EARTH SCIENCE > SOLID EARTH > GEOCHEMISTRY > MARINE GEOCHEMICAL PROCESSES > CHEMICAL DECOMPOSITION
              • keyword
                • CharacterString: EARTH SCIENCE > SOLID EARTH > GEOMORPHIC LANDFORMS/PROCESSES > FLUVIAL PROCESSES > WEATHERING
              • thesaurusName
                • CI_Citation
                  • title
                    • CharacterString: NASA/GCMD Earth Science Keywords
                  • date
                    • CI_Date
                      • date (gco:nilReason=missing): 
                      • dateType
                        • CI_DateTypeCode (codeList=http://www.isotc211.org/2005/resources/Codelist/gmxCodelists.xml#CI_DateTypeCode codeListValue=publication): publication
          • descriptiveKeywords
            • MD_Keywords
              • keyword
                • CharacterString: geological process > sedimentation (geology)
              • thesaurusName
                • CI_Citation
                  • title
                    • CharacterString: GEMET - INSPIRE themes, version 1.0
                  • date
                    • CI_Date
                      • date (gco:nilReason=missing): 
                      • dateType
                        • CI_DateTypeCode (codeList=http://www.isotc211.org/2005/resources/Codelist/gmxCodelists.xml#CI_DateTypeCode codeListValue=publication): publication
          • resourceConstraints (xlink:href=http://creativecommons.org/licenses/by/4.0/)
            • MD_Constraints
              • useLimitation
                • CharacterString: CC BY 4.0
          • resourceConstraints
            • MD_LegalConstraints
              • accessConstraints
                • MD_RestrictionCode (codeList=http://www.isotc211.org/2005/resources/codeList.xml#MD_RestrictionCode codeListValue=otherRestrictions): 
              • otherConstraints
                • CharacterString: CC BY 4.0
          • resourceConstraints
            • MD_SecurityConstraints
              • classification
                • MD_ClassificationCode (codeList=http://www.isotc211.org/2005/resources/codeList.xml#MD_ClassificationCode codeListValue=unclassified): 
          • aggregationInfo
            • MD_AggregateInformation
              • aggregateDataSetIdentifier
                • RS_Identifier
                  • code
                    • CharacterString: 10.1002/2017GL074259
                  • codeSpace
                    • CharacterString: DOI
              • associationType
                • DS_AssociationTypeCode (codeList=http://datacite.org/schema/kernel-4 codeListValue=Continues): Continues
          • aggregationInfo
            • MD_AggregateInformation
              • aggregateDataSetIdentifier
                • RS_Identifier
                  • code
                    • CharacterString: 10.1029/2019GL086061
                  • codeSpace
                    • CharacterString: DOI
              • associationType
                • DS_AssociationTypeCode (codeList=http://datacite.org/schema/kernel-4 codeListValue=IsSupplementTo): IsSupplementTo
          • aggregationInfo
            • MD_AggregateInformation
              • aggregateDataSetIdentifier
                • RS_Identifier
                  • code
                    • CharacterString: 10.1130/G37594.1
                  • codeSpace
                    • CharacterString: DOI
              • associationType
                • DS_AssociationTypeCode (codeList=http://datacite.org/schema/kernel-4 codeListValue=Cites): Cites
          • aggregationInfo
            • MD_AggregateInformation
              • aggregateDataSetIdentifier
                • RS_Identifier
                  • code
                    • CharacterString: 10.1130/GES01063.1
                  • codeSpace
                    • CharacterString: DOI
              • associationType
                • DS_AssociationTypeCode (codeList=http://datacite.org/schema/kernel-4 codeListValue=Cites): Cites
          • aggregationInfo
            • MD_AggregateInformation
              • aggregateDataSetIdentifier
                • RS_Identifier
                  • code
                    • CharacterString: 10.1016/0016-7037(89)90395-5
                  • codeSpace
                    • CharacterString: DOI
              • associationType
                • DS_AssociationTypeCode (codeList=http://datacite.org/schema/kernel-4 codeListValue=Cites): Cites
          • aggregationInfo
            • MD_AggregateInformation
              • aggregateDataSetIdentifier
                • RS_Identifier
                  • code
                    • CharacterString: 10.1016/0016-7037(53)90003-9
                  • codeSpace
                    • CharacterString: DOI
              • associationType
                • DS_AssociationTypeCode (codeList=http://datacite.org/schema/kernel-4 codeListValue=Cites): Cites
          • aggregationInfo
            • MD_AggregateInformation
              • aggregateDataSetIdentifier
                • RS_Identifier
                  • code
                    • CharacterString: 10.1111/j.1751-908X.1995.tb00164.x
                  • codeSpace
                    • CharacterString: DOI
              • associationType
                • DS_AssociationTypeCode (codeList=http://datacite.org/schema/kernel-4 codeListValue=Cites): Cites
          • aggregationInfo
            • MD_AggregateInformation
              • aggregateDataSetIdentifier
                • RS_Identifier
                  • code
                    • CharacterString: 10.1016/j.jas.2017.09.005
                  • codeSpace
                    • CharacterString: DOI
              • associationType
                • DS_AssociationTypeCode (codeList=http://datacite.org/schema/kernel-4 codeListValue=Cites): Cites
          • aggregationInfo
            • MD_AggregateInformation
              • aggregateDataSetIdentifier
                • RS_Identifier
                  • code
                    • CharacterString: http://nbn-resolving.de/urn:nbn:de:gbv:46-ep000103106
                  • codeSpace
                    • CharacterString: URL
              • associationType
                • DS_AssociationTypeCode (codeList=http://datacite.org/schema/kernel-4 codeListValue=Cites): Cites
          • aggregationInfo
            • MD_AggregateInformation
              • aggregateDataSetIdentifier
                • RS_Identifier
                  • code
                    • CharacterString: 10.1007/s10533-005-5879-3
                  • codeSpace
                    • CharacterString: DOI
              • associationType
                • DS_AssociationTypeCode (codeList=http://datacite.org/schema/kernel-4 codeListValue=Cites): Cites
          • aggregationInfo
            • MD_AggregateInformation
              • aggregateDataSetIdentifier
                • RS_Identifier
                  • code
                    • CharacterString: 10.1021/ac50043a017
                  • codeSpace
                    • CharacterString: DOI
              • associationType
                • DS_AssociationTypeCode (codeList=http://datacite.org/schema/kernel-4 codeListValue=Cites): Cites
          • aggregationInfo
            • MD_AggregateInformation
              • aggregateDataSetIdentifier
                • RS_Identifier
                  • code
                    • CharacterString: http://repositorio.uchile.cl/handle/2250/134916
                  • codeSpace
                    • CharacterString: URL
              • associationType
                • DS_AssociationTypeCode (codeList=http://datacite.org/schema/kernel-4 codeListValue=Cites): Cites
          • aggregationInfo
            • MD_AggregateInformation
              • aggregateDataSetIdentifier
                • RS_Identifier
                  • code
                    • CharacterString: 10.1016/0009-2541(95)00157-3
                  • codeSpace
                    • CharacterString: DOI
              • associationType
                • DS_AssociationTypeCode (codeList=http://datacite.org/schema/kernel-4 codeListValue=Cites): Cites
          • aggregationInfo
            • MD_AggregateInformation
              • aggregateDataSetIdentifier
                • RS_Identifier
                  • code
                    • CharacterString: 10.1029/2003JF000049
                  • codeSpace
                    • CharacterString: DOI
              • associationType
                • DS_AssociationTypeCode (codeList=http://datacite.org/schema/kernel-4 codeListValue=Cites): Cites
          • aggregationInfo
            • MD_AggregateInformation
              • aggregateDataSetIdentifier
                • RS_Identifier
                  • code
                    • CharacterString: 10.1002/2017GL074259
                  • codeSpace
                    • CharacterString: DOI
              • associationType
                • DS_AssociationTypeCode (codeList=http://datacite.org/schema/kernel-4 codeListValue=Cites): Cites
          • language
            • CharacterString: eng
          • characterSet
            • MD_CharacterSetCode (codeListValue=utf8 codeList=http://www.isotc211.org/2005/resources/codeList.xml#MD_CharacterSetCode): 
          • topicCategory
            • MD_TopicCategoryCode: geoscientificInformation
          • extent
            • EX_Extent
              • geographicElement
                • EX_GeographicBoundingBox
                  • westBoundLongitude
                    • Decimal: -74.9103
                  • eastBoundLongitude
                    • Decimal: -70.8454
                  • southBoundLatitude
                    • Decimal: -38.1931
                  • northBoundLatitude
                    • Decimal: -36.0738
      • distributionInfo
        • MD_Distribution
          • transferOptions
            • MD_DigitalTransferOptions
              • onLine
                • CI_OnlineResource
                  • linkage
                    • URL: http://doi.org/10.5880/fidgeo.2020.009
                  • protocol
                    • CharacterString: WWW:LINK-1.0-http--link
                  • name
                    • CharacterString: Data Access - DOI
                  • description
                    • CharacterString: Data Access - DOI
                  • function
                    • CI_OnLineFunctionCode (codeList=http://www.isotc211.org/2005/resources/Codelist/gmxCodelists.xml#CI_OnLineFunctionCode codeListValue=http://www.isotc211.org/2005/resources/Codelist/gmxCodelists.xml#CI_OnLineFunctionCode_information): information
      • dataQualityInfo
        • DQ_DataQuality
          • scope
            • DQ_Scope
              • level
                • MD_ScopeCode (codeListValue=dataset codeList=http://www.isotc211.org/2005/resources/codeList.xml#MD_ScopeCode): 
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    License: CC BY 4.0

    Dataset Description

    Supplement to